蛇纹石化和俯冲带蛇纹岩变质脱水过程中流体活动性元素的行为   总被引：1，自引：1，他引：0  

吴凯  袁洪林  吕楠  张丽鹏 《岩石学报》2020,36(1):141-153

蛇纹石是大洋岩石圈和俯冲带内水和流体活动性元素最重要的载体之一。研究蛇纹石化和蛇纹岩变质脱水过程中流体活动性元素的行为是认识俯冲带元素地球化学循环的关键。蛇纹岩是指主要由蛇纹石类矿物构成的岩石,包括利蛇纹石、纤蛇纹石和叶蛇纹石。蛇纹石化过程中会造成流体活动性元素(B、Li、As、Sb、Pb、Cs、U、Sr和Ba等)的显著富集,并且由于原岩性质、流体成分和氧逸度等条件的不同,大洋岩石圈蛇纹岩和弧前蛇纹岩的特征也略有不同。例如,弧前蛇纹岩具有相对高的As、Sb、B和相对低的U,这反映了俯冲沉积物来源流体的贡献。在俯冲带蛇纹岩的变质脱水过程中,利蛇纹石向叶蛇纹石的转变伴随着矿物内超过50%F和Cl的释放,以及一些流体活动性元素(如B和Li)的迁出;此外,蛇纹石分解形成的变质橄榄石中的流体包裹体指示,蛇纹石脱水分解所产生的流体具有高于原始地幔几个数量级的Cl、Cs、Pb、As、Sb、Ba、Rb、B、Sr、Li和U含量。由于利蛇纹石中的Fe~(3+)含量较叶蛇纹石高,这种矿物相转变过程中也伴随着俯冲通道内的一系列氧化还原过程,从而影响流体性质和新形成的叶蛇纹石的成分。蛇纹岩与岛弧岩浆在流体活动性元素富集规律上的相似性说明蛇纹岩在俯冲带元素循环中扮演着重要的角色。此外,蛇纹石矿物相转变过程中F、Cl、B等元素的释放,可能对于斑岩型金矿、蛇绿岩中的金矿和某些蛇纹岩作为赋矿围岩的硼矿的形成起到重要的作用。  相似文献   

Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type     

Li‐Juan Du  Bo Li  Zhi‐Long Huang  Jun Chen  Jia‐Xi Zhou  Guo‐Fu Zou  Zai‐Fei Yan 《Resource Geology》2020,70(1):28-49

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.  相似文献   

New high-resolution 2D seismic imaging of fluid escape structures in the Makran subduction zone,Arabian Sea     

《China Geology》2020,3(2):269-282

Seabed fluid escape is active in the Makran subduction zone, Arabian Sea. Based on the new high-resolution 2D seismic data, acoustic blanking zones and seafloor mounds are identified. Acoustic blanking zones include three kinds of geometries: Bell-shaped, vertically columnar and tilted zones. The bell-shaped blanking zone is characterized by weak and discontinuous reflections in the interior and up-bending reflections on the top, interpreted as gas chimneys. Vertically columnar blanking zone is interpreted as side-imaged gas chimneys associated with focused fluid flow and topped by a seafloor anomaly expressed as a localized reflection discontinuity, which may together serve as a vent structure. Tilted acoustic blanking zone could be induced by accretionary thrust activity and rapid sedimentation surrounding slope. Seafloor mounds occur at the sites of bell-shaped acoustic blanking zone and may be associated with the material intrusion. Bottom simulating refectors (BSRs) are widely distributed and exhibit a series of characteristics including diminished amplitude, low continuity as well as local shoaling overlapping with these acoustic blanking zones. The large amount of gases dissociated from the gas hydrates migrated upwards and then arrived at the near-seafloor sediments, followed by the formation of the gas hydrates and hence the seafloor mound.  相似文献   

Coupling relationship between reservoir diagenesis and hydrocarbon accumulation in Lower Cretaceous Yingcheng Formation of Dongling,Changling fault depression,Songliao Basin,Northeast China     

《China Geology》2020,3(2):247-261

The Lower Cretaceous Yingcheng Formation in the southern Songliao Basin is the typical tight oil sandstone in China. In order to better predict the petrophysical properties of the tight sandstone reservoirs in the Lower Cretaceous Yingcheng Formation, Songliao Basin, Northeast China, the diagenesis and porosity evolution was investigated using a suite of petrographic and geochemical techniques including thin section analysis, scanning electron microscopy, mercury intrusion and fluid inclusion analysis, on a set of selected tight sandstone samples. Combined with the histories of burial evolution, organic matter thermal evolution and hydrocarbon charge, the matching relationship between reservoir porosity evolution and hydrocarbon accumulation history is analyzed. The result showed that the tight sandstone reservoirs characterized of being controlled by deposition, predominated by compaction, improved by dissolution and enhanced by cementation. The hydrocarbon accumulation period was investigated using a suite of hydrocarbon generation and expulsion history, microfluorescence determination and temperature measurement technology. According to the homogenization temperature of the inclusions and the history of burial evolution, Yingcheng Formation has mainly two phases hydrocarbon accumulation. The first phase of oil and gas is charged before the reservoir is tightened, the oil and gas generated by Shahezi source rocks enter the sand body of Yingcheng Formation, influenced by the carrying capability of sand conducting layer, oil and gas is mainly conducted by the better properties and higher connectivity sand body and enriched in the east, which belongs to the type of densification after hydrocarbon accumulation. The second phase of oil and gas charge after densification, which belongs to the type of densification before the hydrocarbon accumulation.  相似文献   

A triple porosity scheme for fluid/solid substitution: theory and experiment     

Yongyang Sun  Boris Gurevich  Maxim Lebedev  Stanislav Glubokovskikh  Vassili Mikhaltsevitch  Junxin Guo 《Geophysical Prospecting》2019,67(4):888-899

Quantifying the effects of pore-filling materials on elastic properties of porous rocks is of considerable interest in geophysical practice. For rocks saturated with fluids, the Gassmann equation is proved effective in estimating the exact change in seismic velocity or rock moduli upon the changes in properties of pore infill. For solid substance or viscoelastic materials, however, the Gassmann theory is not applicable as the rigidity of the pore fill (either elastic or viscoelastic) prevents pressure communication in the pore space, which is a key assumption of the Gassmann equation. In this paper, we explored the elastic properties of a sandstone sample saturated with fluid and solid substance under different confining pressures. This sandstone sample is saturated with octadecane, which is a hydrocarbon with a melting point of 28°C, making it convenient to use in the lab in both solid and fluid forms. Ultrasonically measured velocities of the dry rock exhibit strong pressure dependency, which is largely reduced for the filling of solid octadecane. Predictions by the Gassmann theory for the elastic moduli of the sandstone saturated with liquid octadecane are consistent with ultrasonic measurements, but underestimate the elastic moduli of the sandstone saturated with solid octadecane. Our analysis shows that the difference between the elastic moduli of the dry and solid-octadecane-saturated sandstone is controlled by the squirt flow between stiff, compliant, and the so-called intermediate pores (with an aspect ratio larger than that of compliant pore but much less than that of stiff pores). Therefore, we developed a triple porosity model to quantify the combined squirt flow effects of compliant and intermediate pores saturated with solid or viscoelastic infill. Full saturation of remaining stiff pores with solid or viscoelastic materials is then considered by the lower embedded bound theory. The proposed model gave a reasonable fit to the ultrasonic measurements of the elastic moduli of the sandstone saturated with liquid or solid octadecane. Comparison of the predictions by the new model to other solid substitution schemes implied that accounting for the combined effects of compliant and intermediate pores is necessary to explain the solid squirt effects.  相似文献   

Hydrogeophysical modelling of Hisarcik (Kütahya) geothermal field,western Turkey     

Serkan Üner  Gülçin Özürlan Ağaçgözgü  Doğa Düşünür Doğan 《Geophysical Prospecting》2019,67(8):2176-2195

Western Anatolia hosts many low-to-moderate and high-temperature geothermal sources in which active faults play a dominant role to control the recharge and the discharge of geothermal fluid. In this study, we used the two-dimensional geoelectric structure of Kütahya Hisarcık geothermal field, and created a conceptual hydrogeophysical model that includes faults, real topographical variations and geological units. The temperature distribution and fluid flow pattern are also investigated. The depth extension of Hisarcık Fault, electrical basement and low resistivity anomalies related to the presence of geothermal fluid are determined by using resistivity studies in the area. Numerical simulations suggest that Hisarcık fault functioning as a fluid conduit primarily enables hot fluid to be transported from depth to the surface. It is shown that the locations of predicted outflow vents coincide with those of hot springs in the area.  相似文献   

南北地震带北段流体资料地震预测效能检验     

王博  钟骏  王熠熙  陈石 《地震》2018,38(1):147-156

以南北地震带北段长时间、 连续并有多次震例记录的流体观测资料为研究对象, 使用Molchan图表法对其与周边地震的关系进行了检验和分析, 计算了时间占有率、 预测效能和概率增益等参数。 结果表明, 南北地震带北段各台项的预测效能差别较大。 整体看来, 甘东南地区的观测资料检验效果较好, 表现为概率增益较大; 青海东部地区的多个测项预测效能检验结果较好, 但概率增益较小; 宁夏北部贺兰山东麓断裂附近两台项的报准率差别不大, 但概率增益、 时间占有率等却都不同。 此外, 从前兆资料变化时间上看, 短期异常和长期异常都较多, 中期异常较少。  相似文献   

Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton     

Biswajit Mishra  Kamal Lochan Pruseth  Pranjit Hazarika  Sakthi Saravanan Chinnasam 《地学前缘(英文版)》2018,9(3):715-726

Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include(1) the famous Kolar mine and the world class Hutti deposit;(2) small mines at HiraBuddini, Uti, Ajjanahalli, and Guddadarangavanahalli;(3) prospects at Jonnagiri; and(4) old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous(H_2O + CO_2 ± CH_4 + NaCl) ore fluids,which precipitated gold and altered the host rocks in a narrow P-T window of 0.7-2.5 kbar and 215-320℃. While the calculated fluid O-and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs.magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite, pyrite and arsenopyrite point toward operation of fault-valves that caused pressure fluctuation-induced fluid phase separation, which acted as the dominant process of gold precipitation,apart from fluid-rock sulfidation reactions. Therefore, results from geochemistry of hydrothermal minerals and those from fluid inclusion microthermometry corroborate in constraining source of ore fluid,nature of gold transport(by Au-bisulfide complex) and mechanism of gold ore formation in the Dharwar Craton.  相似文献   

滇西芦子园远程矽卡岩Pb-Zn-Fe(Cu)多金属矿床流体包裹体初探及矿床成因探讨   总被引：4，自引：4，他引：0  

邓明国  陈伟  王学武  刘凤祥  管申进  卢映祥  余海军  赵发 《岩石学报》2018,34(5):1239-1257

滇西镇康芦子园是"三江"成矿带保山地块内迄今发现的唯一超大型Pb-Zn-Fe(Cu)多金属矿床,是区内系列同类层控热液铅锌矿床的典型代表。矿体呈似层状、脉状及透镜状产于寒武系碳酸盐岩建造的矽卡岩和大理岩层间破碎带,矿石构造以条带状、浸染状和脉状-网脉状为主要特征;围岩蚀变复杂、分带明显,由下至上依次为石榴子石-透辉石-透闪石-阳起石化带→绿泥石-绿帘石-阳起石-蔷薇辉石化带→碳酸盐-大理岩化带。矿床成矿流体从早期到晚期经历了多个矿化阶段。本文选取了该矿床早矽卡岩阶段、晚矽卡岩阶段、石英硫化物阶段和石英碳酸盐阶段的多种脉石矿物及闪锌矿进行了系统的流体包裹体研究。结果显示,早矽卡岩阶段发育微溶CO_2富液相和纯液相水溶液包裹体,并含大量K~+、Na~+、Ca~(2+)、F~-和Cl~-和少量SO_4~(2-),气相成分主要为H_2O、CO_2及少量CH_4和N_2,包裹体均一温度为233.6~315.6℃,盐度为10.6%~17.6%NaCleqv;晚矽卡岩阶段发育含CO_2和子矿物三相包裹体,均一温度214.9~388.0℃,盐度5.9%~16.4%NaCleqv;石英硫化物阶段发育含CO_2的水溶液包裹体,气相成分为CH_4、H_2O和少量CO_2,均一温度150.0~285.0℃,盐度为2.5%~13.8%NaCleqv;石英碳酸盐阶段为单一成分的水溶液包裹体,均一温度为105.0~187.5℃,盐度为0.5%~12.3%NaCleqv。结合H-O同位素研究表明,成矿流体最初来源于具中高温、中高盐度、高K、Na,富CO_2、Cl、F等特征的深部岩浆热液,在石英硫化物阶段开始有大气降水混入,演化为中阶段中低温、低盐度、贫CO_2的热液流体,至成矿晚阶段转化为以大气降水占主导。该矿床成矿环境的改变、流体混合以及流体的沸腾作用可能是导致成矿物质富集沉淀的重要机制。综合矿床地质特征、成矿流体包裹体和HO同位素研究认为,该矿床为与陆陆碰撞造山和深部隐伏岩体有关的远程矽卡岩成矿系统。  相似文献   

北衙金矿多期热液成矿作用识别:来自地质、岩相学、流体包裹体和H-O-S同位素证据   总被引：2，自引：2，他引：0  

王璇  杨林  邓军  李华健  于华之  董超一 《岩石学报》2018,34(5):1299-1311

北衙超大型金矿床是三江特提斯成矿域中喜山期斑岩-矽卡岩型矿床的典型代表,长期以来大量研究均围绕斑岩-矽卡岩成矿作用开展并取得了丰硕成果,然而对于北衙金矿是否存在多期热液成矿作用尚不明确。本次研究基于详细野外调查、岩相学与矿相学研究,流体包裹体显微测温及成分分析、H-O-S同位素分析等多种手段,识别了北衙金矿成矿晚期存在新一期热液成矿事件。主要证据如下:(1)野外调查发现北衙金矿发育NW向陡倾断裂控制的石英多金属硫化物脉,其切割矽卡岩矿体与矽卡岩晚期石英硫化物矿脉;(2)本次研究矿脉中原生流体包裹体类型主要为富CO_2三相水溶液包裹体、含CO_2三相水溶液包裹体及气液两相水溶液包裹体,而矽卡岩晚期硫化物脉中除上述三种类型外还发育含子晶三相水溶液包裹体;(3)成矿流体均一温度分布范围为204～426℃,盐度为1.0%～14.2%NaCleqv,整体表现为中高温、中低盐度的NaCl-CO_2-H_2O流体体系,而矽卡岩晚期硫化物脉成矿流体体系具有中温、中高盐度的特征;(4)该矿脉中石英的δ~(18)O、δD范围分别为7.5‰～9.4‰与-102.0‰～-75.0‰,指示岩浆水来源,而矽卡岩晚期硫化物脉具有岩浆水和大气水混合来源。本次研究的多金属硫化物矿脉δ~(34)S值范围为-0.97‰～1.40‰,与矽卡岩期和矽卡岩晚期硫化物脉中黄铁矿S同位素一致,表明多期矿化成矿物质均具有幔源贡献。结合北衙矿集区成岩成矿动力学背景,推测始新世大规模地壳拆沉、软流圈上涌导致的强烈的壳幔相互作用可能是北衙金矿多期成矿作用的诱因。  相似文献